E.I. Du Pont De Nemours & Co. v. MacDermid Printing Solutions, L.L.C. ( 2016 )


Menu:
  •        NOTE: This disposition is nonprecedential.
    United States Court of Appeals
    for the Federal Circuit
    ______________________
    E.I. DU PONT DE NEMOURS AND COMPANY,
    Plaintiff-Appellant
    v.
    MACDERMID PRINTING SOLUTIONS, L.L.C.,
    Defendant-Appellee
    ______________________
    2015-1777
    ______________________
    Appeal from the United States District Court for the
    District of New Jersey in No. 3:06-cv-03383-MLC-TJB,
    Judge Mary L. Cooper.
    ______________________
    Decided: August 19, 2016
    ______________________
    CHARLES E. LIPSEY, Finnegan, Henderson, Farabow,
    Garrett & Dunner, LLP, Reston, VA, argued for plaintiff-
    appellant. Also represented by HOWARD WARREN LEVINE,
    AARON GLEATON CLAY, Washington, DC; MARY K.
    FERGUSON, Boston, MA; JENNIFER SWAN, JEFFREY DANIEL
    SMYTH, Palo Alto, CA; MATTHEW JOSEPH RICCIARDI,
    CHARLES D. OSSOLA, Vinson & Elkins LLP, Washington,
    DC.
    2        E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    JOHN RICHARD HORVACK, JR., Carmody Torrance San-
    dak & Hennessey LLP, New Haven, CT, argued for de-
    fendant-appellee. Also represented by FATIMA LAHNIN.
    ______________________
    Before PROST, Chief Judge, PLAGER and LOURIE, Circuit
    Judges.
    LOURIE, Circuit Judge.
    E.I. du Pont de Nemours & Co. (“DuPont”) appeals
    from the decision of the United States District Court for
    the District of New Jersey granting summary judgment
    that claims 1, 6, 22, 30, 33, 36, 39–41, and 48 of U.S.
    Patent 6,773,859 (“the ’859 patent”) are invalid as obvi-
    ous, and that claims 1, 3–4, and 7–8 of U.S. Patent
    6,171,758 (“the ’758 patent”), as construed by the district
    court, were not infringed by MacDermid Printing Solu-
    tions, L.L.C. (“MacDermid”). See E.I. du Pont de Nemours
    & Co. v. MacDermid Printing Sols., L.L.C., No. 06-3383,
    
    2014 WL 4657300
    (D.N.J. Sept. 17, 2014) (“Summary
    Judgment Order”); E.I. du Pont de Nemours & Co. v.
    MacDermid Printing Sols., L.L.C., No. 06-3383, 
    2010 WL 988549
    (D.N.J. Mar. 15, 2010) (“Claim Construction
    Order”). Because the district court did not err in granting
    summary judgment of invalidity of the ’859 patent or in
    granting summary judgment of noninfringement of the
    ’758 patent, we affirm.
    BACKGROUND
    A
    DuPont owns the ’859 patent, directed to a process of
    making a flexographic printing plate used to print images
    on flexible materials. The ’859 patent claims priority
    from a provisional application filed on March 6, 2001, ’859
    patent, Certificate of Corr. dated July 26, 2005; see also
    E.I. du Pont de Nemours & Co. v. MacDermid Printing
    Sols., L.L.C., 
    525 F.3d 1353
    , 1362–63 (Fed. Cir. 2008), and
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    3
    was considered by the district court to have a date of
    invention on or before June 9, 1999, Summary Judgment
    Order, 
    2014 WL 4657300
    , at *9.
    A flexographic printing plate bearing the image to be
    printed is typically prepared from an “imaging” process
    and a “development” process. As shown below, a flexo-
    graphic printing plate consists of multiple layers, includ-
    ing a base support layer and a photopolymerizable layer,
    which contains photoinitiators, monomers, and elastomer-
    ic binders. During the imaging process, selected areas of
    the photopolymerizable layer are exposed to ultraviolet
    (“UV”) light, which causes the exposed areas to polymer-
    ize. The unpolymerized material is then removed in the
    development process, leaving the polymerized material on
    the plate, which forms the relief image to be printed.
    Joint App. (“J.A.”) 3692.
    As of June 1999, there existed two methods for imag-
    ing: analog and digital. Summary Judgment Order, 
    2014 WL 4657300
    , at *16. Analog imaging was first developed
    in the 1950s. In analog imaging, a sheet bearing a nega-
    tive of the image to be printed is placed on top of the
    photopolymerizable layer. A transparent coversheet is
    then placed over the negative. The plate is then exposed
    to UV light, which passes through the transparent areas
    of the negative and causes the exposed portions of the
    photopolymerizable layer to polymerize. The opaque
    areas of the negative block the UV light and thus prevent
    the photopolymerizable layer underneath those areas
    from polymerizing. After the removal of the coversheet
    and negative, the unpolymerized portions of the photo-
    polymerizable layer are removed in the development
    4      E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    process, leaving only the relief image. The analog imag-
    ing process is illustrated below.
    J.A. 3692–93.
    In 1992, DuPont developed the digital imaging tech-
    nology, in which a thin, opaque infrared ablation layer is
    applied over the photopolymerizable layer. That ablation
    layer can block UV light, but can be removed by an infra-
    red laser. Thus, one difference between a digital plate
    and an analog plate is that a digital plate has an ablation
    layer. In digital imaging, the image to be printed is
    digitized and stored in a computer. The computer then
    guides an infrared laser to imagewise remove, or ablate,
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    5
    select portions of the ablation layer. That process creates
    an in-situ mask directly on top of the photopolymerizable
    layer. The plate is then exposed to UV light, and the
    openings in the in-situ mask allow the UV light to pass
    through, such that the exposed portions of the photopoly-
    merizable layer undergo polymerization. The unpoly-
    merized material, together with the ablation layer above
    it, is then removed in the development process. The
    digital imaging process is illustrated below.
    J.A. 3697–99.
    The “development” process follows the “imaging” pro-
    cess. As of June 1999, there existed the following devel-
    opment techniques: solvent, water, air knife, and thermal.
    6      E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    Summary Judgment Order, 
    2014 WL 4657300
    , at *16.
    According to DuPont, solvent and thermal development
    methods have been known since at least the 1960s.
    Appellant’s Br. 2. The solvent development method uses
    chemical solvents to wash and remove the unpolymerized
    portions of the photopolymerizable layer. According to
    DuPont, although solvent development requires the use of
    chemical solvents, which posed certain environmental
    risks, the combination of analog imaging and solvent
    development has been widely used for decades. 
    Id. at 11–
    12. When DuPont developed digital imaging in the 1990s,
    it initially used the solvent method to develop the digital-
    ly imaged plates. That combination of digital imaging
    and solvent development is described in DuPont’s U.S.
    Patent 5,262,275 (“Fan”), J.A. 2421–29, which is prior art
    to the ’859 patent.
    In contrast, the thermal development method uses
    heat to soften or liquefy the unpolymerized portions of the
    photopolymerizable layer, and then uses absorbent mate-
    rial, such as paper or felt, to blot away the unpolymerized
    material. The prior art, including U.S. Patent 5,175,072
    (“Martens”), J.A. 2182–99, describes the combination of
    analog imaging and thermal development.
    DuPont’s ’859 patent claims a process for making a
    flexographic printing plate that combines digital imaging
    and thermal development techniques. Claim 30 is illus-
    trative of the ’859 patent claims at issue in this appeal.
    Reproduced in independent form, claim 30 reads:
    30. A process for making a flexographic printing
    plate comprising:
    1) providing a photosensitive element com-
    prising: at least one photopolymerizable
    layer on a support comprising an elasto-
    meric binder, at least one monomer, and a
    photoinitiator, and at least one thermally
    removable layer disposed above the photo-
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.      7
    polymerizable layer, wherein the thermal-
    ly removable layer is
    (a) an actinic radiation opaque layer com-
    prising (i) at least one infrared absorb-
    ing material, (ii) a radiation opaque
    material, wherein (i) and (ii) can be
    the same or different, and at least one
    binder having a softening or melting
    temperature less than 190º C;
    2) imagewise exposing the photopolymeriza-
    ble layer to actinic radiation forming poly-
    merized portions and unpolymerized
    portions; and
    3) thermally treating the element of step 2)
    by heating to a temperature sufficient to
    remove the thermally removable layer and
    to remove the unpolymerized portions of
    the photopolymerizable layer and form a
    relief.
    ’859 patent col. 43 ll. 14–40, col. 46 ll. 26–27 (emphases
    added). Thus, step 1(a) of the claimed method requires a
    digital plate with an ablation layer that is thermally
    removable. Step 2 refers to the digital imaging process,
    and step 3 refers to the thermal development process, in
    which both the unpolymerized photopolymerizable mate-
    rial and the ablation layer above it are thermally re-
    moved. According to DuPont, it commercialized its digital
    thermal technology as Digital Cyrel® FAST in 2001.
    Appellant’s Br. 21.
    B
    DuPont also owns the ’758 patent, directed to a flexo-
    graphic printing plate having a very low degree of distor-
    tion during thermal development, the plate comprising a
    “dimensionally stable” polymeric substrate. ’758 patent,
    at [57] (abstract); 
    id. col. 1
    ll. 51–60. The ’758 patent
    8        E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    issued in January 2001 from an application filed in 1994.
    Claim 1 reads as follows:
    1.    A photosensitive plate suitable for use as a
    flexographic printing plate comprising a
    dimensionally stable, flexible, polymeric sub-
    strate and a photosensitive elastomer layer,
    wherein the plate has a thermal distortion in
    both the machine and the transverse direc-
    tions which is less than 0.03% when the plate
    is exposed to actinic radiation and, after ex-
    posure, is developed at temperatures between
    100 and 180º C.
    
    Id. col. 8
    ll. 18–25 (emphases added). Claims 3–4 and 7–8
    all depend, directly or indirectly, from claim 1.
    The specification of the ’758 patent teaches that the
    dimensional stability of the polymeric substrate “may be
    controlled through a special annealing process,” 
    id. col. 2
    ll. 56–59 (emphasis added), and then describes the an-
    nealing process in detail, 
    id. col. 2
    l. 59–col. 3 l. 40. The
    specification also describes four examples, in which all of
    the annealed plates showed less thermal distortion than
    the unannealed control plates. 
    Id. col. 5
    l. 26–col. 7 l. 67.
    Moreover, the specification teaches that the substrate
    “optionally may be surface treated for better adhesion”
    and cites two prior art patents as disclosing such an
    optional adhesive bonding process. 
    Id. col. 3
    l. 66–col. 4
    l. 5 (emphasis added). During prosecution, the patentee
    relied on the special annealing process, and characterized
    it as “critical” and “important” in order to overcome
    inherent anticipation and obviousness rejections. E.g.,
    J.A. 2303–04, 2346–47, 2348, 2365, 2367.
    C
    In April 2006, DuPont sued MacDermid in the United
    States District Court for the District of Colorado, alleging
    that MacDermid infringed the ’859 and ’758 patents.
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.     9
    
    DuPont, 525 F.3d at 1355
    ; Summary Judgment Order,
    
    2014 WL 4657300
    , at *1. In July 2006, the case was
    transferred from the District of Colorado to the District of
    New Jersey. 
    DuPont, 525 F.3d at 1355
    .
    The district court construed the “dimensionally sta-
    ble” limitation in claim 1 of the ’758 patent. Claim Con-
    struction Order, 
    2010 WL 988549
    , at *5–9. The parties
    disputed whether “dimensionally stable” should be con-
    strued as requiring the “special annealing process” de-
    scribed in the ’758 patent, and the court agreed with
    MacDermid that “dimensionally stable” is so limited. 
    Id. at *5,
    *7. The court reasoned that the specification “re-
    peatedly highlights the importance of annealing” in
    achieving the claimed dimensional stability, and that
    during prosecution, the applicants “repeatedly empha-
    sized the whole notion of annealing” in order to overcome
    prior-art-based rejections. 
    Id. at *7.
    The court therefore
    adopted MacDermid’s proposed construction of “dimen-
    sionally stable,” which is:
    A flexible polymeric substrate whose dimensional
    stability has been controlled through a special an-
    nealing process, namely an annealing process
    that: (1) is in addition and subsequent to the heat
    treating steps associated with manufacturing the
    polymeric film, (2) is not the process of bonding
    the photosensitive elastomer layer to the polymer-
    ic substrate, and (3) comprises: (i) heating the
    substrate to a temperature above its glass transi-
    tion temperature but below its melting tempera-
    ture and at or greater than the temperature to
    which the substrate is later subjected during
    thermal development, (ii) at tensions of less than
    200 psi, and (iii) for a time greater than the time
    required to bring the film to the annealing tem-
    perature, such that a specially annealed substrate
    has less thermally induced distortion than a non-
    specially annealed substrate.
    10       E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    
    Id. at *5,
    *9.
    MacDermid then filed motions for summary judgment
    of, inter alia, invalidity of the ’859 patent and nonin-
    fringement of the ’758 patent. The district court granted
    summary judgment in favor of MacDermid on both issues.
    Summary Judgment Order, 
    2014 WL 4657300
    , at *1.
    The district court granted summary judgment that
    claims 1, 6, 22, 30, 33, 36, 39–41, and 48 of the ’859 patent
    would have been obvious over the cited prior art, includ-
    ing Martens and Fan. 1 
    Id. at *9–20.
    The court found that
    Martens teaches a process for developing an analog plate
    using heat, 
    id. at *10,
    and that Fan “was the first digital
    imaging patent,” which teaches developing a digital plate
    using solvents, 
    id. at *11.
    The court found that the pro-
    cess claimed in the ’859 patent utilizes not only “the same
    technology and processes pertaining to digital imaging” as
    disclosed in Fan, but also “the same process of thermal
    development” as disclosed in Martens. 
    Id. at *13.
        The district court then found that there were “several
    reasons that would have prompted a person of ordinary
    skill to combine digital imaging technology and thermal
    development technology in the same way as the ’859
    patent.” 
    Id. at *16.
    In particular, the court found that:
    1  In the district court, MacDermid also cited the fol-
    lowing patent references to support its obviousness mo-
    tion: (1) European Patent EP 0 741 330, U.S. Patent
    5,888,697, and U.S. Patent 5,925,500, as purportedly
    teaching digital imaging; and (2) European Patent EP
    0 665 471, International Patent Application Publication
    WO96/14603, U.S. Patent 3,264,103, U.S. Patent
    5,279,697, U.S. Patent 5,322,761, and U.S. Patent
    5,925,500, as purportedly teaching thermal development.
    J.A. 2937–38. But the district court primarily relied on
    Fan and Martens in its obviousness analysis.
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    11
    (1) there existed only two imaging and four development
    techniques, id.; (2) the prior art taught that digital imag-
    ing has certain benefits over analog imaging, and that
    thermal development has certain advantages over solvent
    development, id.; (3) thus, a person of ordinary skill would
    have been motivated “to combine digital imaging and
    thermal development in one sequential process to gain the
    benefits of both,” id.; (4) DuPont detailed the benefit of
    digital imaging in a 1997 article, describing digital plates
    as “truly superior,” and also detailed the benefit of ther-
    mal development at an April 1999 tradeshow, touting
    thermal development as “revolutionary,” 
    id. at *16–17
    (internal quotation marks omitted); and (5) thus, market
    forces would have “created a strong incentive” for a person
    of ordinary skill to combine “the revolutionary thermal
    process . . . with the truly superior digital plates,” and
    “one only needed to place a truly superior digital plate
    (after imagewise exposure) into a revolutionary thermal
    process,” or alternatively, “to upgrade an analog-thermal
    plate in a known manner to . . . a digital-thermal plate,”
    
    id. at *17
    (internal quotation marks omitted).
    The district court considered objective evidence of
    nonobviousness in the record, but found such evidence
    insufficient to preclude summary judgment. 
    Id. at *18–
    19. The court criticized DuPont for “sensationaliz[ing]”
    the commercial success of its digital thermal Cyrel prod-
    uct because its own expert stated in his declaration that
    “marketplace acceptance of Cyrel was not immediate,”
    and that “only through working with initial customers . . .
    DuPont was able to develop a market for thermally devel-
    oped plates over time.” 
    Id. at *18
    (internal quotation
    marks omitted). The court also criticized DuPont’s com-
    mercial success evidence on the bases that (1) DuPont
    provided percentage growth of yearly sales, “but fail[ed] to
    put those figures into context”; (2) DuPont presented
    evidence that Cyrel generated over $90 million in sales
    from 2001 to 2006, but failed to “document more revealing
    12     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    statistics, such as its profits”; (3) DuPont failed to men-
    tion that all thermally developed plates, including those
    other than Cyrel, accounted for only 13% of the overall
    U.S. market for flexographic printing plates; and
    (4) DuPont’s dominant position in the flexographic print-
    ing plate market “reduce[d] the impact” of its proffered
    evidence of commercial success. 
    Id. at *18–
    19. The court
    thus concluded that DuPont failed to adequately establish
    a nexus between the claimed invention and its purported
    commercial success. 
    Id. at *19.
        The district court also rejected DuPont’s argument of
    long-felt (seven years from 1992 to 1999) but unmet need
    because DuPont failed to establish a palpable need for
    digital thermal plates that existed for a long time. 
    Id. Lastly, the
    court considered DuPont’s evidence of industry
    praise, namely, the Flexographic Technical Association’s
    Technical Innovation Award for DuPont’s Cyrel product.
    The court acknowledged that the award “may be at least
    some evidence of industry praise,” but nevertheless con-
    cluded that it was “vastly insufficient to overcome Mac-
    Dermid’s strong showing of obviousness.” 
    Id. The court
    therefore concluded that the asserted claims of the ’859
    patent are invalid as obvious. 
    Id. at *20.
         The district court next considered MacDermid’s mo-
    tion for summary judgment of noninfringement of the ’758
    patent. 
    Id. at *20–25.
    MacDermid argued that its ac-
    cused Digital CST plate did not contain a “dimensionally
    stable” substrate because the manufacturing process of
    the accused plate did not involve the “special annealing
    process” required by the claims under the district court’s
    construction. 
    Id. at *20.
    DuPont sought to rely on an
    adhesive drying process used by MacDermid’s contractor,
    Kimoto, to establish that the “dimensionally stable”
    limitation was met, but MacDermid introduced evidence
    to show that the adhesive drying process was not a “spe-
    cially annealing process” that “controls” the “dimensional
    stability” of the substrate. 
    Id. E.I. DU
    PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    13
    The district court reasoned that under its construction
    of “dimensionally stable,” the process of bonding the
    photosensitive layer to the polymeric substrate is not a
    “special annealing process.” 
    Id. at *23.
    It then found that
    Kimoto’s adhesive drying process is part of the bonding
    process, and thus not an annealing process. 
    Id. The court
    therefore granted summary judgment of noninfringement
    of claims 1, 3–4, and 7–8 of the ’758 patent. 
    Id. Following the
    district court’s grant of summary judg-
    ment, DuPont moved for entry of final judgment under
    Federal Rule of Civil Procedure 54(b). The district court
    granted DuPont’s motion and entered final judgment.
    DuPont timely appealed to this court. We have jurisdic-
    tion under 28 U.S.C. § 1295(a)(1).
    DISCUSSION
    When reviewing a district court’s grant of summary
    judgment, we apply the law of the regional circuit in
    which the district court sits, here, the Third Circuit. Teva
    Pharm. Indus. Ltd. v. AstraZeneca Pharm. LP, 
    661 F.3d 1378
    , 1381 (Fed. Cir. 2011). The Third Circuit “review[s]
    an order granting summary judgment de novo, applying
    the same standard” used by the district court. Azur v.
    Chase Bank, USA, Nat’l Ass’n, 
    601 F.3d 212
    , 216 (3d Cir.
    2010) (quotation omitted). Summary judgment is appro-
    priate when, drawing all justifiable inferences in the
    nonmovant’s favor, “there is no genuine dispute as to any
    material fact and the movant is entitled to judgment as a
    matter of law.” Fed. R. Civ. P. 56(a); Anderson v. Liberty
    Lobby, Inc., 
    477 U.S. 242
    , 247–48 (1986). DuPont chal-
    lenges the district court’s grants of summary judgment of
    invalidity of the ’859 patent and of noninfringement of the
    ’758 patent. We review each of those decisions in turn.
    A
    Obviousness is ultimately a question of law premised
    on underlying issues of fact, including: (1) the scope and
    14     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    content of the prior art; (2) the level of ordinary skill in
    the pertinent art; (3) the differences between the claimed
    invention and the prior art; and (4) objective evidence
    such as commercial success, long-felt need, and the failure
    of others. KSR Int’l Co. v. Teleflex Inc., 
    550 U.S. 398
    , 427
    (2007); Graham v. John Deere Co., 
    383 U.S. 1
    , 17–18
    (1966). A patent claim is invalid as obvious if an alleged
    infringer proves that the differences between the claimed
    subject matter and the prior art are such that the subject
    matter as a whole would have been obvious at the time of
    invention to a person having ordinary skill in the art. 35
    U.S.C. § 103(a) (2006). Patents are presumed to be valid,
    and overcoming that presumption requires clear and
    convincing evidence. 35 U.S.C. § 282; Microsoft Corp. v.
    i4i Ltd. P’ship, 
    564 U.S. 91
    , 95 (2011).
    DuPont argues that the district court failed to draw
    reasonable inferences in its favor. DuPont asserts that
    the district court improperly relied on “market forces” and
    hindsight in finding a reason to combine digital imaging
    and thermal development. DuPont contends that digital
    imaging generated high quality plates, but that prior art
    thermal processes yielded poor quality plates. DuPont
    notes that Fan, the first digital imaging patent, teaches
    only solvent development. Thus, DuPont continues, a
    skilled artisan would not have had a reason to use digital
    imaging to obtain a high quality image and then degrade
    that image with thermal development. DuPont also
    contends that Martens’s thermal process is not the same
    as the claimed process because Martens does not describe
    a thermally removable ablation layer. DuPont argues
    that one would not have reasonably expected that the
    thermal process would successfully remove the ablation
    layer bound to the photopolymerizable layer necessary for
    digital imaging. DuPont additionally argues that the
    district court failed to properly consider the objective
    evidence, including unexpected results, copying by Mac-
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    15
    Dermid, commercial success, long-felt but unmet need,
    and industry praise.
    MacDermid responds that the district court correctly
    found “several reasons” for a skilled artisan to combine
    digital and thermal technologies, including market forces,
    limited prior art options of the imaging and development
    processes, and known benefits of digital imaging and
    thermal development. MacDermid also points to printed
    publications prior to March 6, 2000, the § 102(b) critical
    date, which explicitly describe combining digital imaging
    and thermal development. MacDermid notes, moreover,
    that DuPont’s digital-solvent plates sold before the
    § 102(b) critical date contain the same opaque infrared
    ablation layer as its later-marketed digital-thermal
    plates. Finally, MacDermid responds that the district
    court properly considered the objective evidence before
    reaching its ultimate conclusion of obviousness, and that
    DuPont’s objective evidence was sparse and without the
    required nexus.
    We agree with MacDermid that the asserted claims of
    the ’859 patent would have been obvious at the time of the
    invention over the cited prior art. It is undisputed that
    digital imaging and thermal development are techniques
    known in the prior art. In the district court, DuPont
    conceded that “the prior art contained various ‘digital
    solvent’ references (e.g., [Fan] . . . , DuPont’s DPU plate,
    and MacDermid’s CBU plates) that disclosed steps 1(a)
    and 2” of the claimed method, and also “contained various
    ‘analog thermal’ references (e.g., [Martens] . . . ) that
    disclosed one or more layers above a photopolymerizable
    layer.” J.A. 7397. DuPont maintains, however, that the
    prior art does not teach or suggest the thermally remova-
    ble ablation layer of step 1(a). DuPont also argues that a
    person of ordinary skill in the art would not have had a
    reason to carry out the claimed process of thermally
    developing a digitally imaged plate, and would not have
    16     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    had a reasonable expectation of success in doing so. We
    disagree.
    The district court correctly found that a person of or-
    dinary skill in the art would have had a reason to combine
    digital imaging and thermal development in the same
    way as claimed in the ’859 patent. DuPont does not
    dispute that there were a finite number of options of
    imaging and development methods. Thus, a person of
    ordinary skill only needed to traverse finite prior art
    options by substituting one known technique for another.
    More importantly, the prior art highlights the ad-
    vantages of digital imaging over analog imaging. In a
    1997 article, entitled “The Digital Difference,” J.A. 4193,
    published five years after the digital-solvent technology
    was invented, DuPont’s inventors reported that “digital
    plates print with finer highlights while retaining deeper
    shadows, and with lower dot gain than conventional
    printing throughout the tonal range,” J.A. 4196. They
    described digital imaging as “truly superior,” “gaining
    worldwide acceptance,” and “a fundamental technology
    improvement that enables expansion of the flexographic
    printing process into . . . new markets,” noting that orders
    for digital plates and digital exposure devices were “stead-
    ily increasing.” J.A. 4193, 4196, 4197.
    The prior art also describes the advantages of thermal
    development over solvent development.          Martens, a
    patent issued in December 1992, teaches that those
    advantages include “a substantial reduction of plate
    making steps, plate making process time, and the elimi-
    nation of potentially toxic by-product waste streams in
    plate making.” Martens at 4:23–34. Martens also de-
    scribes actual examples that produced “excellent” images
    after thermal development. 
    Id. at 21:67–22:2,
    26:21–22.
    Moreover, in April 1999, DuPont detailed the benefits of
    its Cyrel® FAST thermal technology at a U.S. tradeshow,
    describing the technology as “revolutionary,” “a great leap
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.   17
    forward,” and a “breakthrough technology” that “reduce[s]
    platemaking time.” J.A. 3420. DuPont emphasized that,
    as compared to solvent development, the thermal method
    reduced platemaking time from over 3 hours to 1 hour
    and produced “high quality” plates. 
    Id. Accordingly, the
    prior art teaches significant benefits
    of both digital imaging and thermal development over
    their counterparts, providing a reason for a person of
    ordinary skill to combine them in one sequential process.
    Indeed, in a January 2000 article, published more than
    one year before the earliest application filing date, and
    thus qualifying as prior art under 35 U.S.C. § 102(b)
    (2006), 2 a DuPont consultant stated that “[d]igitally
    imaged plates will become the standard for high-quality
    flexo,” and that “Next on the horizon is Cyrel FAST,
    reportedly the first thermal, dry-processed flexo plate-
    maker on the market. Regular or digitally imaged plates
    are processed without solvents or liquids.” J.A. 3427
    (emphases added). That article thus explicitly and unam-
    biguously teaches combining digital and thermal technol-
    ogies, thus laying to rest any doubt whether there would
    have been a reason to combine those technologies.
    We are unpersuaded by DuPont’s arguments to the
    contrary. DuPont only relies on its expert’s declaration
    and identifies no prior art that disparages the claimed
    combination. DuPont argues that the thermal method
    produced poor quality images, and thus it had languished
    2    This court and our predecessor court have held
    that art considered to be a statutory bar under § 102(b)
    qualifies as prior art under § 103(a). See, e.g., Dippin’
    Dots, Inc. v. Mosey, 
    476 F.3d 1337
    , 1344 (Fed. Cir. 2007);
    LaBounty Mfg., Inc. v. ITC, 
    958 F.2d 1066
    , 1071 (Fed. Cir.
    1992); In re Kaslow, 
    707 F.2d 1366
    , 1374 (Fed. Cir. 1983);
    In re Ownby, 
    471 F.2d 1233
    , 1236 (CCPA 1973); In re
    Foster, 
    343 F.2d 980
    , 988–90 (CCPA 1965).
    18     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    for decades since the 1960s. But, as the record shows, in
    the 1990s, right before the 1999 date of invention, several
    prior art references, including Martens and DuPont’s own
    public disclosures, promoted the thermal process. Even if
    it were true that the thermal process was not the best
    method for producing high quality images, the legally
    proper question is whether the thermal process would be
    a suitable option in some respects, not necessarily in every
    respect. Here, the prior art teaches the benefits of ther-
    mal development over solvent development, including
    environmental and time-saving benefits. There is there-
    fore no genuine issue of material fact that a person of
    ordinary skill would have had a reason to combine digital
    imaging and thermal development.
    We also agree with MacDermid that a person of ordi-
    nary skill in the art would have had a reasonable expecta-
    tion of success in combining digital imaging and thermal
    development as claimed by the ’859 patent. As indicated,
    DuPont conceded that the prior art “digital” references
    teach steps 1(a) and 2 of the claimed method, and that the
    prior art “thermal” references teach the thermal removal
    of multiple layers. DuPont also admitted that its prior-
    art digital-solvent plates have the same chemical compo-
    sition as its digital-thermal plates. J.A. 3384–85, 3237.
    Although the prior art did not explicitly teach the thermal
    removal of the ablation layer in a digital plate, the record
    shows that prior art digital plates already included abla-
    tion layers with binders that softened and flowed at
    thermal development temperatures, and thus are in fact
    thermally removable. Accordingly, there would have been
    a reasonable expectation that the thermal process would
    successfully remove the ablation layer bound to the photo-
    polymerizable layer.
    This is not a case where a skilled artisan needed “to
    vary all parameters or try each of numerous possible
    choices until one possibly arrived at a successful result,
    where the prior art gave either no indication of which
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.     19
    parameters were critical or no direction as to which of
    many possible choices is likely to be successful.” In re
    O’Farrell, 
    853 F.2d 894
    , 903 (Fed. Cir. 1988). Nor is this
    a case where a skilled artisan “was to explore a new
    technology or general approach that seemed to be a prom-
    ising field of experimentation, where the prior art gave
    only general guidance as to the particular form of the
    claimed invention or how to achieve it.” 
    Id. Notably, the
    claims at issue do not require any special
    condition for digital imaging or thermal development.
    With a reason to combine digital and thermal technolo-
    gies, a skilled artisan needed only to begin from an exist-
    ing digital plate, to imagewise expose it, and then to
    thermally develop the plate in known ways to practice the
    claimed process. Thus, the claimed process would at least
    have been obvious to try. There is therefore no genuine
    issue of material fact that a person of ordinary skill in the
    art would have had a reasonable expectation of success in
    combining digital and thermal techniques.
    DuPont lastly contends that secondary considerations
    created a triable issue precluding summary judgment.
    Because this appeal arises from a grant of summary
    judgment, as with other issues, we review the objective
    evidence de novo, drawing all justifiable inferences in
    favor of DuPont. Fed. R. Civ. P. 56(a). In district court
    litigation, courts must consider all objective evidence
    before reaching the ultimate conclusion of obviousness. In
    re Cyclobenzaprine Hydrochloride Extended-Release
    Patent Litig., 
    676 F.3d 1063
    , 1076 (Fed. Cir. 2012). “The
    objective considerations, when considered with the bal-
    ance of the obviousness evidence in the record, guard as a
    check against hindsight bias.” 
    Id. at 1079.
    The burden of
    persuasion remains on the patent challenger to prove
    obviousness. 
    Id. at 1077–78.
        DuPont argues that the district court failed to proper-
    ly consider the objective evidence, including unexpected
    20     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    results, copying, commercial success, long-felt but unmet
    need, and industry praise. On a careful review of the
    record, we agree with MacDermid that DuPont’s purport-
    ed evidence of unexpected results, copying, and long-felt
    but unmet need is sparse. Moreover, drawing all justifia-
    ble inferences in favor of DuPont, we conclude that the
    proffered objective evidence, including commercial success
    and industry praise, is insufficient to create a genuine
    issue of material fact to preclude summary judgment.
    As discussed, the record contains strong evidence that
    a skilled artisan would have had a reason to combine two
    known technologies and would have had a reasonable
    expectation of success in doing so. Indeed, DuPont itself
    promoted the digital and thermal technologies as techno-
    logical breakthroughs in prior art publications. Thus, in
    view of the record as a whole, even drawing all justifiable
    inferences in favor of DuPont, the objective evidence is
    insufficient to preclude summary judgment on the ulti-
    mate legal conclusion of obviousness.
    We therefore affirm the grant of summary judgment
    of invalidity of the ’859 patent.
    B
    We now turn to the district court’s grant of summary
    judgment of noninfringement of the ’758 patent. To
    determine infringement, a court first construes the scope
    and meaning of the asserted patent claims, and then
    compares the construed claims to the accused product or
    process. Absolute Software, Inc. v. Stealth Signal, Inc.,
    
    659 F.3d 1121
    , 1129 (Fed. Cir. 2011). “The proper con-
    struction of a patent’s claims is an issue of Federal Circuit
    law.” 
    Id. We review
    a district court’s ultimate claim
    construction de novo and any underlying factual determi-
    nations involving extrinsic evidence for clear error. Teva
    Pharm. U.S.A., Inc. v. Sandoz, Inc., 
    135 S. Ct. 831
    , 841–
    42 (2015). Here, because the district court relied solely on
    the intrinsic record in construing the challenged claim
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    21
    term, and because the intrinsic record alone determines
    the proper construction, we review the district court’s
    construction de novo. See Shire Dev., LLC v. Watson
    Pharm., Inc., 
    787 F.3d 1359
    , 1364, 1368 (Fed. Cir. 2015)
    (citing 
    Teva, 135 S. Ct. at 840
    –42).
    Infringement is a question of fact. Absolute 
    Software, 659 F.3d at 1129
    –30. “On appeal from a grant of sum-
    mary judgment of non-infringement, we determine
    whether, after resolving reasonable factual inferences in
    favor of the patentee, the district court correctly conclud-
    ed that no reasonable jury could find infringement.” 
    Id. 1 The
    words of a claim “are generally given their ordi-
    nary and customary meaning” as understood by a person
    of ordinary skill in the art at the time of the invention.
    Phillips v. AWH Corp., 
    415 F.3d 1303
    , 1312–13 (Fed. Cir.
    2005) (en banc). The court looks to the intrinsic record,
    including “the words of the claims themselves, the re-
    mainder of the specification, [and] the prosecution histo-
    ry,” as well as to extrinsic evidence when appropriate, to
    construe a disputed claim term. 
    Id. at 1314.
        DuPont argues that the district court erred in con-
    struing “dimensionally stable” by importing a “special
    annealing” process limitation into a product claim and by
    imposing further requirements that the annealing process
    take place after the manufacturing of the polymeric film
    and be separate from the bonding process. DuPont argues
    that there was no disclaimer or disavowal during prosecu-
    tion because it merely discussed the annealing process to
    show that the inherency rejection was improper.
    MacDermid responds that the district court did not
    impermissibly read process limitations into the product
    claims. MacDermid argues that the “special annealing
    process” is a necessary limitation because the patentee
    emphasized during prosecution that the “special anneal-
    22     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    ing process” is essential to the claimed invention. Mac-
    Dermid argues, moreover, that the specification makes
    clear that the annealing process is the invention, whereas
    the bonding process is optional and disclosed by the prior
    art.
    We agree with MacDermid that the district court did
    not err in construing “dimensionally stable” as requiring a
    “special annealing process” that controls the dimensional
    stability of the polymeric substrate, as described in the
    patent specification. During prosecution, the applicants
    relied solely on that annealing process to overcome prior-
    art-based anticipation and obviousness rejections and
    repeatedly characterized the annealing process as “im-
    portant” and “critical.” J.A. 2303, 2348, 2367. Those
    statements constitute a disclaimer of the claim scope.
    We are unpersuaded by DuPont’s argument that its
    prosecution statements were made merely to show that
    the examiner failed to establish that the prior art plates,
    which were not annealed, inherently possess the claimed
    dimensional stability. As noted, the applicants sought to
    overcome both inherency and obviousness rejections, and
    it repeatedly emphasized that the annealing process is
    “important” and “critical.” The applicants did so to secure
    issuance, and succeeded. In view of the disclaimer in the
    publicly available intrinsic record, DuPont cannot now
    attempt to recapture the disclaimed subject matter.
    We therefore conclude that the “dimensionally stable”
    limitation requires that the polymeric substrate be pre-
    pared from the special annealing process that controls the
    dimensional stability of the substrate. We need not, and
    do not, address whether the district court erred in requir-
    ing that the annealing process be separate from the
    bonding process because, as indicated infra, our affir-
    mance of the grant of summary judgment of noninfringe-
    ment does not turn on that issue.
    E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.    23
    2
    DuPont next argues that, even under the district
    court’s construction, the court erred in granting summary
    judgment of noninfringement because it resolved factual
    disputes in favor of MacDermid as to whether the accused
    process, namely, Kimoto’s adhesive drying process, is a
    “special annealing process.” MacDermid responds that it
    was entitled to summary judgment because DuPont relied
    solely on one sentence in its expert report, stating that
    the Kimoto process is not a bonding process, to establish
    that the Kimoto process is an annealing process. Mac-
    Dermid notes that DuPont’s expert later conceded that
    the Kimoto process is for bonding, not other purposes.
    MacDermid additionally argues that the record sup-
    ports alternative grounds for affirming the grant of sum-
    mary judgment of noninfringement, including DuPont’s
    failure to establish that the dimensional stability of the
    accused substrate is “controlled” by a “special annealing
    process.” DuPont responds that MacDermid’s alleged
    alternative grounds involve disputed issues of fact, not
    law, and thus must be decided by a jury on remand.
    We agree with MacDermid and affirm the grant of
    summary judgment of noninfringement on the alternative
    ground that DuPont failed to establish that the dimen-
    sional stability of the accused substrate is controlled by
    the accused Kimoto adhesive drying process.
    In the district court, MacDermid presented evidence
    that the dimensional stability of the accused substrate
    was not improved by Kimoto’s adhesive drying process.
    DuPont did not put forth any contrary evidence on this
    issue. In opposition to MacDermid’s motion for summary
    judgment, DuPont filed an expert declaration attempting
    to provide, for the first time, an analysis and opinion that
    the Kimoto process controlled dimensional stability. J.A.
    7275–79. The district court struck DuPont’s newly dis-
    closed evidence, J.A. 13283–94, and DuPont does not
    24     E.I. DU PONT DE NEMOURS   v. MACDERMID PRINTING SOLS.
    challenge that evidentiary ruling on appeal. Thus, with-
    out evidence that the Kimoto process controls the dimen-
    sional stability of the accused substrate, no reasonable
    jury could find that MacDermid infringes the asserted
    claims.
    We therefore affirm the grant of summary judgment
    of noninfringement of the ’758 patent.
    CONCLUSION
    We have considered DuPont’s remaining arguments
    and find them unpersuasive. For the foregoing reasons,
    we conclude that the asserted claims of the ’859 patent
    would have been obvious in view of the prior art and that
    the asserted claims of the ’758 patent were not infringed.
    We therefore affirm the judgment of the district court.
    AFFIRMED